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I too have seen this...

 

and was fortunate/unfortunate enough to watch it as it happened. I have never seen this is a watch before but when I was in my first watchmaking school we used to also service clocks. I had this happen on 2-3 mainsprings that has mild surface rust. These were treated with a  mild acid treatment to remove the rust prior to lubricating and installing in the the barrels. In one of the instances it didn't even last long enough to finish preparing the barrel lid before I started hearing the familiar sound of a bowl of Rice Krispies. Upon closer inspection it was clear to see the individual cracks appearing as the pressure of the mainspring seemed to be shattering itself. It was like watching popcorn pop.

I had assumed it was due to the rust removal method causing the steel to become brittle, however further study was not undertaken.

TCP

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